Chloridobis(ethylenediamine-κ2 N,N′)(n-pentylamine-κN)cobalt(III) dichloride monhydrate
نویسندگان
چکیده
The title complex, [CoCl(C(5)H(13)N)(C(2)H(8)N(2))(2)]Cl(2)·H(2)O, comprises one chloridobis(ethyl-enediamine)(n-pentyl-amine)cobalt(III) cation, two chloride counter-anions and a water mol-ecule. The Co(III) atom of the complex is hexa-coordinated by five N and one Cl atoms. The five N atoms are from two chelating ethyl-enediamine and one n-pentyl-amine ligands. Neighbouring cations and anions are connected by N-H⋯Cl and N-H⋯O hydrogen bonds to each other and also to the water mol-ecule.
منابع مشابه
(Ethylenediamine-κ2 N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN 1]cobalt(III) nitrate monohydrate
In the title compound, [Co(C(8)H(6)N(3))(2)(C(2)H(8)N(2))]NO(3)·H(2)O, the Co(III) ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethyl-enediamine in a distorted octa-hedral geometry. In the crystal, classical N-H⋯N(O) and O-H⋯N(O) hydrogen bonds connect all the isolated components together to yield a three-dimensional structure.
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